COMPUTATIONAL AND SPECTROSCOPIC CHARACTERIZATIONS OF SOME N-ALKYL (BENZYL)-DIAZENIUM DIOLATES AND THEIR METAL COMPLEXES

Full Article - PDF

Published: 2015-01-15

Page: 1-13


OLGA KOVALCHUKOVA *

Department of General Chemistry, People’s Friendship University of Russia, Russia

ALI SHEIKH BOSTANABAD

Department of Chemistry, Amirkabir University of Technology, Iran

MICHAEL RYABOV

Department of General Chemistry, People’s Friendship University of Russia, Russia

NASRIN NAMICHEMAZI

Department of General Chemistry, People’s Friendship University of Russia, Russia

IGOR ZYUZIN

Institute of Problems of Chemical Physics, Russian Academy of Sciences, Russia

TEIMURAZ BERIKASHVILI

Department of Physics, Georgian Technical University, Georgia

*Author to whom correspondence should be addressed.


Abstract

The molecular and electronic structures and spectroscopic characteristics of a series of N-alkyl(benzyl)-N-nitroso hydroxylaminesat deprotonation (diazenium diolates) and complex formation were studied by computational (DFT/ B3LYP) and spectroscopic (UV-VIS) methods. Molecular and electronic structures as well as the bond character in the complexes with the metal ions of various natures are described. The results of the DFT calculations do not contradict the crystal structure determination data and the spectral characteristics of the complexes.

 

Keywords: Nalkyl(benzyl)diazenium diolates, potassium salts, metal complexes, DFT calculations, spectroscopic characteristics


How to Cite

KOVALCHUKOVA, O., BOSTANABAD, A. S., RYABOV, M., NAMICHEMAZI, N., ZYUZIN, I., & BERIKASHVILI, T. (2015). COMPUTATIONAL AND SPECTROSCOPIC CHARACTERIZATIONS OF SOME N-ALKYL (BENZYL)-DIAZENIUM DIOLATES AND THEIR METAL COMPLEXES. Journal of Applied Chemical Science International, 1(1), 1–13. Retrieved from https://ikprress.org/index.php/JACSI/article/view/2703

Downloads

Download data is not yet available.