Journal of Applied Chemical Science International

1,4-DINITROGEN NUCLEOPHILES IN THE BREAKING OF THE Cα=Cβ MULTIPLE BOND IN 2-FERROCENYLMETHYLIDENE-β-DICARBONYL COMPOUNDS. SIMPLE METHOD FOR THE PREPARATION OF THE Al(III) COMPLEXES WITH β-DIKETONES AND -β-KETOESTERS

JESSICA J. SÁNCHEZ GARCÍA

Faculty of Chemistry, National Autonomous University of Mexico, C.P. 04510 México D.F., México

MIGUEL A. GALLARDO VEGA

Faculty of Chemistry, National Autonomous University of Mexico, C.P. 04510 México D.F., México

MARCOS FLORES-ALAMO

Faculty of Chemistry, National Autonomous University of Mexico, C.P. 04510 México D.F., México

JOSÉ M. MÉNDEZ STIVALET

Faculty of Chemistry, National Autonomous University of Mexico, C.P. 04510 México D.F., México

ELENA I. KLIMOVA *

Faculty of Chemistry, National Autonomous University of Mexico, C.P. 04510 México D.F., México

*Author to whom correspondence should be addressed.

---

Abstract

The reactions of the compounds 2-ferrocenylmethylidene-β-diketones and -β-ketoesters with 1,4-dinitrogen nucleophiles were studied. A new reaction of breaking the C_α=C_β multiple bond in 2-ferrocenylmethy-lidene-β-dicarbonyl compounds is found. The structures of the target compounds [2-ferrocenylbenzimidazoles, 2-(ferrocenylmethylidenamino)anilines, 2-amino-3-(ferrocenylmethyliden-amino)pyridines, 4-amino-5-(ferrocenylmethylidenamino)pyrimidine, aluminum complexes with β-dicarbonyl compounds] are established using IR, ¹H and ¹³C NMR spectroscopy, mass spectrometry, elemental analysis and X-ray diffraction analysis.

 

Keywords: Ferrocene, 2-Ferrocenylmethylidene-β-dicarbonyl compounds, 1,4-Dinitrogen nucleophiles, Breaking of the Cα=Cβ multiple bond, Aluminum (III) complexes

---

---