SYNTHESIS, GROWTH AND SPECTRAL STUDIES ON THIOSEMICARBAZIDE ZINC(II) PICRATE

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Published: 2015-10-01

Page: 322-330


R. SANTHAKUMARI *

Department of Physics, Government Arts College for Women (Autonomous), Pudukkottai- 622 001, Tamil Nadu, India

K. RAMAMURTHI

Crystal Growth and Thin Film Laboratory, Department of Physics and Nanotechnology, Faculty of Engineering and Technology, SRM University, Kattankulathur-603 203, Tamil Nadu, India

R. RAMESH BABU

Crystal Growth and Thin Film Laboratory, Department of Physics, Bharathidasan University, Tiruchirappalli-620 024, Tamil Nadu, India

*Author to whom correspondence should be addressed.


Abstract

Thiosemicarbazide zinc(II) picrate (TSCZP) was synthesized and its solubility in the dimethyl sulfoxide and dimethyl formamide solvents was estimated. 0.01g of TSCZP was dissolved in 100cc of dimethyl sulfoxide and dimethyl formamide separately and the conductivity of the solution was measured using conductivity meter. Three dimensional crystal structure of the grown crystal was determined by single crystal X-ray diffraction study. The TSCZP crystallizes in the triclinic system with space group P-1. The presence of the functional groups were confirmed from the Fourier Transform Infrared spectral studies. UV-vis-NIR spectral studies show that the transmittance between 385 and 1100 nm is about 60%. Thermogravimetric and differential thermal analyses reveal the thermal stability of the crystal. The microhardness test was carried out, and the load hardness parameter was measured.

Keywords: A1. Characterization, A2. Growth from solution, B1. Organic compound


How to Cite

SANTHAKUMARI, R., RAMAMURTHI, K., & BABU, R. R. (2015). SYNTHESIS, GROWTH AND SPECTRAL STUDIES ON THIOSEMICARBAZIDE ZINC(II) PICRATE. Journal of Applied Chemical Science International, 4(4), 322–330. Retrieved from https://ikprress.org/index.php/JACSI/article/view/3465

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